When attenpting to install a Linux Distro, its common to download the ISO then use a tool (e.g. UNetbootin, Linux Live USB Creator, Universal USB Installer, Live USB Creator) to make a USB bootable with the installer of the distro. This is no the recommended way.
https://wiki.archlinux.org/index.php/USB_flash_installation_media
To list USB devices
diskutil listUSB devices will appear as something like /dev/disk2 (external, physical), confirm the desired device by the SIZE if more than one.
Unmount device (replace X with disk number)
diskutil unmountDisk /dev/diskX
Then, to copy the content
sudo dd if=path/to/image.iso of=/dev/rdiskX bs=1m
To list USB devices
sudo fdisk -lIdentify device, then run next command, replacing sdX with devices identifier.
sudo dd bs=4M if=/path/to/image.iso of=/dev/sdX && sync